Control of the coil-to-globule transition and ultrahigh mechanical properties of PNIPA in nanocomposite hydrogels

被引：318

作者：

Haraguchi, K ^{[1
]}

Li, HJ ^{[1
]}

机构：

[1] Kawamura Inst Chem Res, Mat Chem Lab, Sakura, Chiba 2850078, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 40期

关键词：

gels; mechanical properties; nanostructures; organic-inorganic hybrid composites; phase transitions;

D O I：

10.1002/anie.200502004

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Figure Presented) Polymer clay for chemists: High strengths and high fracture energies of polymeric hydrogels have been demonstrated by incorporating a substantial amount of nanodispersed inorganic clay during the in situ free-radical polymerization of N-isopropylacrylamide. By varying the amount of clay used, mechanical properties as well as the swelling and transparency of the nanocomposite (NC) could be controlled (see picture; NC20 contains more clay than NC5). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6500 / 6504

页数：5

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