Surface modification of multiwalled carbon nanotubes by poly(2-vinylpyridine):: Dispersion, selective deposition, and decoration of the nanotubes

被引:100
作者
Lou, XD
Detrembleur, C
Pagnoulle, C
Jérôme, R
Bocharova, V
Kiriy, A
Stamm, M
机构
[1] Univ Liege, CERM, B-4000 Liege, Belgium
[2] Inst Polymerforsch, D-01069 Dresden, Germany
关键词
D O I
10.1002/adma.200400298
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer modification of carbon nanotubes is accomplished using a "grafting-to" approach. Radicals formed by the thermolysis of poly(2-vinylpyridine) terminated with a radical-stabilizing nitroxide can react with the surface of nanotubes (see Figure), resulting in grafting densities up to 12 wt.-%. The modified nanotubes. which are easily dispersed in water. can immobilize metal nanoclusters on their surfaces.
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页码:2123 / +
页数:6
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