Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

被引：82

作者：

Lee, DH

Patel, BP

Clot, E

Eisenstein, O

Crabtree, RH

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Montpellier 2, LSDSMS, UMR 5636, F-34095 Montpellier 5, France

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 03期

关键词：

D O I：

10.1039/a808601j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Experimental and theoretical studies show that H-2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H-2 or an Lr-H ... H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.

引用

页码：297 / 298

页数：2

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