Capability of detection of an analytical method evaluating false positive and false negative (ISO 11843) with partial least squares

被引：104

作者：

Ortiz, MC

Sarabia, LA

Herrero, A

Sánchez, MS

Sanz, MB

Rueda, ME

Giménez, D

Meléndez, ME

机构：

[1] Univ Burgos, Fac Ciencias, Dept Quim, Burgos 09001, Spain

[2] Univ Burgos, Fac Ciencias, Dept Matemat & Computac, Burgos 09001, Spain

来源：

CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS | 2003年 / 69卷 / 1-2期

关键词：

PLS calibration; ISO norms; capability of detection; minimum detectable net concentration; detection limit; quantification limit; UV spectroscopy; stripping voltammetry; fluorescence spectroscopy; flow system with electrochemical detection; Triazines; copper; cadmium; lead; selenium; naphthalene; phenol; 4-nitrophenol;

D O I：

10.1016/S0169-7439(03)00110-2

中图分类号：

TP [自动化技术、计算机技术];

学科分类号：

0812 ;

摘要：

Analytical techniques based on soft multivariate calibrations (as those which provide first and second order analytical signals necessarily are) remain outside the field of application of the ISO norms related to capability of detection. In this work, a complete solution for the problem of applying ISO norm 11843 to soft calibration (for instance, one or multi-way partial least squares (PLS)) is provided. The methodological procedure is applied to different case studies which implies different analytical techniques. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：21 / 33

页数：13

共 18 条

[1] [Anonymous], 1997, 11843 ISO
[2] THEORY OF ANALYTICAL-CHEMISTRY
BOOKSH, KS
KOWALSKI, BR
[J]. ANALYTICAL CHEMISTRY, 1994, 66 (15) : A782 - A791
[3] Multivariate detection limits with fixed probabilities of error
Boqué, R
Larrechi, MS
Rius, FX
[J]. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1999, 45 (1-2) : 397 - 408
[4] DETECTION LIMITS WITH SPECIFIED ASSURANCE PROBABILITIES
CLAYTON, CA
HINES, JW
ELKINS, PD
[J]. ANALYTICAL CHEMISTRY, 1987, 59 (20) : 2506 - 2514
[5] Detection and quantification limits: origins and historical overview
Currie, LA
[J]. ANALYTICA CHIMICA ACTA, 1999, 391 (02) : 127 - 134
[6] DRAPER NR, 1981, APPLIED REGRESSION A, pCH1
[7] Faber K, 1997, J CHEMOMETR, V11, P419, DOI 10.1002/(SICI)1099-128X(199709/10)11:5<419::AID-CEM486>3.0.CO
[8] 2-#
[9] FORINA M, 2001, Q PARVUS 3 0 EXT PAC
[10] OPTIMIZATION OF THE EXPERIMENTAL PARAMETERS IN THE DETERMINATION OF COPPER(II) BY DIFFERENTIAL-PULSE ANODIC-STRIPPING VOLTAMMETRY AND EVALUATION OF THE CHARACTERISTIC DETECTION CURVES
HERRERO, A
ORTIZ, MC
ARCOS, MJ
LOPEZPALACIOS, J
[J]. ANALYST, 1994, 119 (07) : 1585 - 1592

← 1 2 →