Velocity of sound and elastic properties of lanthanum gallo-germanate glasses

The velocity of sound in a group of lanthanum gallo-germanate glasses is obtained by the ultrasonic pulse-echo measurements, at room temperature. Both longitudinal and transverse velocities of these glasses are composition dependence. The experimental results are used to obtain the elastic constants. The correlation of elastic stiffness, the cross-link density, and the fractal bond connectivity of these glasses are discussed. The derived experimental values of Young's modulus, bulk modulus, shear modulus and Poisson's ratio for our glasses are compared with those theoretically calculated values in terms of the Makishima-Mackenzie model. A possible existence of tetrahedral (four-fold coordination) and/or octahedral (six-fold coordination) of Ga and Ge in the structure of these glasses is discussed. (c) 2005 Elsevier B.V All rights reserved.