New tetraphenylethene-based efficient blue luminophors: aggregation induced emission and partially controllable emitting color

被引:191
作者
Huang, Jing [2 ]
Yang, Xiao [1 ]
Wang, Jinyu [2 ]
Zhong, Cheng [2 ]
Wang, Lei [1 ]
Qin, Jingui [2 ]
Li, Zhen [2 ]
机构
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Optoelect Sci & Engn, Wuhan 430074, Peoples R China
[2] Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China
基金
美国国家科学基金会;
关键词
DERIVATIVES; DEVICES; ENHANCEMENT;
D O I
10.1039/c1jm14054j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
In this paper, two new TPE-based conjugated molecules, constructed using tetraphenylethene (TPE) and carbazole or spirofluorene moieties, have been successfully prepared. They exhibited aggregation induced emission (AIE) properties, high thermal and morphological stabilities, and low oxidation potential, making them promising properties for optoelectric materials. The fabricated non-doped multilayer OLEDs demonstrate that devices using these luminophors as the emitting layer show relatively good performance, and the device of SFTPE gives a maximum luminance and efficiency of 8196 cd m(-2) and 3.33 cd A(-1), respectively, with the maximum emission wavelength at about 466 nm, thanks to the adjusted molecular structure and AIE characteristic of TPE.
引用
收藏
页码:2478 / 2484
页数:7
相关论文
共 30 条
[1]
High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer [J].
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
NATURE, 2000, 403 (6771) :750-753
[2]
Practical synthesis of unsymnetrical tetraarylethylenes and their application for the preparation of [triphenylethylene-spacer-triphenylethylene] triads [J].
Banerjee, Moloy ;
Emond, Susanna J. ;
Lindeman, Sergey V. ;
Rathore, Rajendra .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (21) :8054-8061
[3]
White organic light-emitting devices for solid-state lighting [J].
D'Andrade, BW ;
Forrest, SR .
ADVANCED MATERIALS, 2004, 16 (18) :1585-1595
[4]
New Carbazole-Based Fluorophores: Synthesis, Characterization, and Aggregation-Induced Emission Enhancement [J].
Dong, Shoucheng ;
Li, Zhen ;
Qin, Jingui .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (02) :434-441
[5]
Aggregation-induced emissions of tetraphenylethene derivatives and their utilities as chemical vapor sensors and in organic light-emitting diodes [J].
Dong, Yongqiang ;
Lam, Jacky W. Y. ;
Qin, Anjun ;
Liu, Jianzhao ;
Li, Zhen ;
Tang, Ben Zhong .
APPLIED PHYSICS LETTERS, 2007, 91 (01)
[6]
Vapochromism of hexaphenylsilole [J].
Dong, YQ ;
Lam, JWY ;
Li, Z ;
Qin, AJ ;
Tong, H ;
Dong, YP ;
Feng, XD ;
Tang, BZ .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2005, 15 (02) :287-291
[7]
Frisch M.J., 2003, GAUSSIAN 09 REVISION
[8]
SYNTHESIS OF FUSIBLE AND SOLUBLE CONDUCTING POLYFLUORENE DERIVATIVES AND THEIR CHARACTERISTICS [J].
FUKUDA, M ;
SAWADA, K ;
YOSHINO, K .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (10) :2465-2471
[9]
Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices [J].
Grimsdale, Andrew C. ;
Chan, Khai Leok ;
Martin, Rainer E. ;
Jokisz, Pawel G. ;
Holmes, Andrew B. .
CHEMICAL REVIEWS, 2009, 109 (03) :897-1091
[10]
Aggregation-induced emission: phenomenon, mechanism and applications [J].
Hong, Yuning ;
Lam, Jacky W. Y. ;
Tang, Ben Zhong .
CHEMICAL COMMUNICATIONS, 2009, (29) :4332-4353