Organocatalytic chain scission of poly(lactides): a general route to controlled molecular weight, functionality and macromolecular architecture

被引:90
作者
Nederberg, F
Connor, EF
Glausser, T
Hedrick, JL
机构
[1] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA
[2] IBM Corp, Ctr Polymer Interfaces & Macromol Assemblies, San Jose, CA 95120 USA
关键词
D O I
10.1039/b106125a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile, single-step transesterification approach to poly(lactides) with controlled molecular weights and end-group functionality, as well as block and star-shaped architectures is described using nucleophilic amine catalysts.
引用
收藏
页码:2066 / 2067
页数:2
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