Reactivity of organic compounds in superheated water: General background

被引：214

作者：

Siskin, M

Katritzky, AR

机构：

[1] ExxonMobile Res & Engn Co, Corp Strateg Res Labs, Annandale, NJ 08801 USA

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 04期

关键词：

D O I：

10.1021/cr000088z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactivity of organic compounds in superheated water was discussed. The ability of water to carry out condensation, cleavage and hydrolysis reactions and to effect selective ionic chemistry was found to be due to the changes in its chemical and physical properties. Water can also act as an acidic or basic catalyst and its reactivity can be reinforced by autocatalysis from water soluble reaction products.

引用

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页码：825 / 835

页数：11

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