Cd(ClO4)2•xH2O as a novel catalyst for the synthesis of α-aminophosphonates under solvent-free conditions

被引：28

作者：

Dindulkar, Someshwar D. ^{[1
]}

Reddy, Mudumala Veeranarayana ^{[1
]}

Jeong, Yeon Tae ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Image Sci & Engn, Pusan 608737, South Korea

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 17卷

关键词：

Cd(ClO4)(2)center dot xH(2)O; One-pot reaction; alpha-aminophosphonates; Solvent-free conditions; ONE-POT SYNTHESIS; SCHIFF-BASES; PHOSPHONATES; ACIDS; HYDROPHOSPHONYLATION; PHOSPHONOPEPTIDES; ALDEHYDES; IMINES; CDI2;

D O I：

10.1016/j.catcom.2011.10.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

In this paper, we report cadmium perchlorate hydrate to be an novel, expeditious catalyst for the three-component one-pot reaction of an amine, an aldehyde and a H-phosphonate diesters in open air without any solvent, leads to alpha-aminophosphonates in excellent yields. To the best of our knowledge this finding is the first example of a cadmium perchlorate hydrate catalyzed Kabachnik-Fields reaction. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：114 / 117

页数：4

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