Nickel-Catalyzed C-O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates

被引：101

作者：

Molander, Gary A. ^{[1
]}

Beaumard, Floriane ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana A Vagelos Labs, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 18期

关键词：

CROSS-COUPLING REACTIONS; GENERAL PALLADIUM CATALYST; SUZUKI-MIYAURA; ARYL MESYLATES; ARYLBORONIC ACIDS; BORONIC ACIDS; ARENESULFONATES; TOSYLATES; SCOPE; COMPLEXES;

D O I：

10.1021/ol101592r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general method based on nickel-catalyzed C-O activation of various phenol derivatives with potassium (hetero)aryltrifluoroborates has been developed. A large number of heterobiaryls can be easily obtained with yields up to 99% using methanesulfonate cross-coupling partners.

引用

页码：4022 / 4025

页数：4

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