A comparative study of the electronic structure and spectroelectrochemical properties of electrosynthesized polyaniline films and nanotubes

被引:33
作者
Dauginet-De Pra, L [1 ]
Demoustier-Champagne, S [1 ]
机构
[1] Catholic Univ Louvain, Unite Chim & Phys Hauts Polymeres, B-1348 Louvain, Belgium
关键词
polyaniline nanotubes brushes; supported templates; electronic structure; spectroelectrochemical properties;
D O I
10.1016/j.tsf.2004.12.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
New nanoporous polymeric templates supported on conductive substrates (gold-coated Si wafers or indium-tin oxide glass) were used to electrosynthesize polyaniline (PANI) nanotubes brushes. X-ray photoelectron, Raman and UV-Vis-NIR spectroscopies were used to characterize the polymer structure, doping level, charge carriers and electronic structure in PANI nanotubes. For the first time, we also report on the redox behavior of PANI nanotubes studied by in situ UV-Vis spectroelectrochemistry. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:321 / 328
页数:8
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