Characterization of Plant Exudates by Principal-Component and Cluster Analyses with Nuclear Magnetic Resonance Variables

被引:16
作者
Lambert, Joseph B. [1 ]
Heckenbach, Eric A. [1 ]
Wu, Yuyang [1 ]
Santiago-Blay, Jorge A. [2 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Smithsonian Inst, Natl Museum Nat Hist, Dept Paleobiol, Washington, DC 20013 USA
来源
JOURNAL OF NATURAL PRODUCTS | 2010年 / 73卷 / 10期
关键词
IONIZATION MASS-SPECTROMETRY; NMR; CLASSIFICATION; RESINS; URINE;
D O I
10.1021/np100318n
中图分类号
Q94 [植物学];
学科分类号
071001 [植物学];
摘要
Principal-component and cluster analyses have been applied to nuclear magnetic resonance data for exudates derived from both conifers and angiosperms in order to classify these materials on the basis of molecular structure. The method succeeds in distinguishing resins produced by the conifer families Araucariaceae, Cupressaceae, and Pinaceae from each other and from resins produced by the angiosperm family Fabaceae. Other exudate types, including gums, gum resins, and kinos, also are distinguished from each other and from the resins.
引用
收藏
页码:1643 / 1648
页数:6
相关论文
共 22 条
[1]
Direct exposure electron ionization mass spectrometry and gas chromatography/mass spectrometry techniques to study organic coatings on archaeological amphorae [J].
Colombini, MP ;
Modugno, F ;
Ribechini, E .
JOURNAL OF MASS SPECTROMETRY, 2005, 40 (05) :675-687
[3]
Application of nuclear magnetic resonance spectroscopy to the analysis of organic archaeological materials [J].
Ghisalberti, EL ;
Godfrey, IM .
STUDIES IN CONSERVATION, 1998, 43 (04) :215-230
[4]
IDENTIFICATION OF ARCHAEOLOGICAL AND RECENT WOOD TAR PITCHES USING GAS-CHROMATOGRAPHY MASS-SPECTROMETRY AND PATTERN-RECOGNITION [J].
HAYEK, EWH ;
KRENMAYR, P ;
LOHNINGER, H ;
JORDIS, U ;
MOCHE, W ;
SAUTER, F .
ANALYTICAL CHEMISTRY, 1990, 62 (18) :2038-2043
[5]
The classification of solvents by combining classical QSPR methodology with principal component analysis [J].
Katritzky, AR ;
Fara, DC ;
Kuanar, M ;
Hur, E ;
Karelson, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (45) :10323-10341
[6]
Taxonomic and chemical relationships revealed by nuclear magnetic resonance spectra of plant exudates [J].
Lambert, JB ;
Wu, YY ;
Santiago-Blay, JA .
JOURNAL OF NATURAL PRODUCTS, 2005, 68 (05) :635-648
[7]
Nuclear magnetic resonance in archaeology [J].
Lambert, JB ;
Shawl, CE ;
Stearns, JA .
CHEMICAL SOCIETY REVIEWS, 2000, 29 (03) :175-182
[8]
LAMBERT JB, 1997, TRACES PAST
[9]
Characterization of eucalyptus and chemically related exudates by nuclear magnetic resonance spectroscopy [J].
Lambert, Joseph B. ;
Wu, Yuyang ;
Kozminski, Michael A. ;
Santiago-Blay, Jorge A. .
AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (11) :862-870
[10]
Distinctions among conifer exudates by proton magnetic resonance spectroscopy [J].
Lambert, Joseph B. ;
Kozminski, Michael A. ;
Santiago-Blay, Jorge A. .
JOURNAL OF NATURAL PRODUCTS, 2007, 70 (08) :1283-1294