Thiylation of polyelectrophiles with sulfur in hydrazine hydrate-amine systems

被引：22

作者：

Deryagina, EN ^{[1
]}

Levanova, EP ^{[1
]}

Grabel'nykh, VA ^{[1
]}

Sukhomazova, EN ^{[1
]}

Russavskaya, NV ^{[1
]}

Korchevin, NA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2005年 / 75卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1007/s11176-005-0197-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thiylation of polyhaloalkanes and Paraform with elemental sulfur activated in hydrazine hydrate-organic amine systems is performed. Monoethanolamine, triethanolamine, and triethylamine were used as amines. The reactions gave thiocols of various structures. The products were characterized by elemental analysis and IR spectroscopy. Reductive cleavage of the synthesized thiocols was performed to obtain di- and polythiols.

引用

页码：194 / 199

页数：6

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