Hexoctahedral Au Nanocrystals with High-Index Facets and Their Optical and Surface-Enhanced Raman Scattering Properties

被引:163
作者
Hong, Jong Wook
Lee, Su-Un
Lee, Young Wook
Han, Sang Woo [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
基金
新加坡国家研究基金会;
关键词
TRISOCTAHEDRAL GOLD NANOCRYSTALS; CORE-SHELL NANOCRYSTALS; PLATINUM NANOCRYSTALS; RHOMBIC DODECAHEDRA; METAL NANOCRYSTALS; ALLOY NANOCRYSTALS; GROWTH; NANOPARTICLES; CATALYSTS; PLANES;
D O I
10.1021/ja300598u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Au nanocrystals (NCs) with an unprecedented hexoctahedral structure enclosed exclusively by high-index {321} facets have been prepared for the first time. Manipulating the NC growth kinetics by controlling the amount of reductant and the reaction temperature in the presence of a suitable surfactant was the key synthetic lever for controlling the morphology of the Au NCs. The hexoctahedral Au NCs exhibited efficient optical and surface-enhanced Raman scattering activities due to their unique morphological characteristics.
引用
收藏
页码:4565 / 4568
页数:4
相关论文
共 36 条
[1]  
[Anonymous], 2004, CRC HDB CHEM PHYS, P8
[2]  
Chiu CY, 2011, NAT CHEM, V3, P393, DOI [10.1038/nchem.1025, 10.1038/NCHEM.1025]
[3]   Shaping binary metal nanocrystals through epitaxial seeded growth [J].
Habas, Susan E. ;
Lee, Hyunjoo ;
Radmilovic, Velimir ;
Somorjai, Gabor A. ;
Yang, Peidong .
NATURE MATERIALS, 2007, 6 (09) :692-697
[4]   One-pot synthesis and electrocatalytic activity of octapodal Au-Pd nanoparticles [J].
Hong, Jong Wook ;
Lee, Young Wook ;
Kim, Minjung ;
Kang, Shin Wook ;
Han, Sang Woo .
CHEMICAL COMMUNICATIONS, 2011, 47 (09) :2553-2555
[5]   Etching Growth under Surface Confinement: An Effective Strategy To Prepare Mesocrystalline Pd Nanocorolla [J].
Huang, Xiaoqing ;
Tang, Shaoheng ;
Yang, Jing ;
Tan, Yueming ;
Zheng, Nanfeng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (40) :15946-15949
[6]   Amine-Assisted Synthesis of Concave Polyhedral Platinum Nanocrystals Having {411} High-Index Facets [J].
Huang, Xiaoqing ;
Zhao, Zipeng ;
Fan, Jingmin ;
Tan, Yueming ;
Zheng, Nanfeng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (13) :4718-4721
[7]   Polyhedral Au Nanocrystals Exclusively Bound by {110} Facets: The Rhombic Dodecahedron [J].
Jeong, Gyoung Hwa ;
Kim, Minjung ;
Lee, Young Wook ;
Choi, Wonjun ;
Oh, Won Taek ;
Park, Q-Han ;
Han, Sang Woo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1672-+
[8]   Palladium Concave Nanocubes with High-Index Facets and Their Enhanced Catalytic Properties [J].
Jin, Mingshang ;
Zhang, Hui ;
Xie, Zhaoxiong ;
Xia, Younan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (34) :7850-7854
[9]   Real-Space Mapping of the Strongly Coupled Plasmons of Nanoparticle Dimers [J].
Kim, Deok-Soo ;
Heo, Jinhwa ;
Ahn, Sung-Hyun ;
Han, Sang Woo ;
Yun, Wan Soo ;
Kim, Zee Hwan .
NANO LETTERS, 2009, 9 (10) :3619-3625
[10]   Convex Polyhedral Au@Pd Core-Shell Nanocrystals with High-Index Facets [J].
Kim, Dongheun ;
Lee, Young Wook ;
Lee, Sang Bok ;
Han, Sang Woo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (01) :159-163