A copper(I) iodide chain with the 2-amino-4,6-dimethylpyridine cation

被引：13

作者：

Haddad, SF ^{[1
]}

AlDamen, MA

Willett, RD

Twamley, B

机构：

[1] Univ Jordan, Dept Chem, Amman 11942, Jordan

[2] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[3] Univ Idaho, Univ Res Off, Moscow, ID 83844 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536803027715

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (2-amino-4,6-dimethylpyridinium) diiodocuprate(I), (C7H11N2)[CuI2], the planar 2-amino-4,6-dimethylpyridine species is protonated at the pyridine N atom. It interacts with the inorganic chains by extensive hydrogen bonding. The cation forms N-H...I hydrogen bonds from both its pyridine and amine N atoms. The copper(I) species is tetrahedrally bonded to four iodide ions (average Cu-I distance=2.665 Angstrom, with a standard uncertainty of 0.019 Angstrom) and forms infinite edge-sharing chains. Atom-site symmetries: Cu (2); I, phenyl-C and N (m).

引用

页码：M76 / M78

页数：3

共 16 条

[1] Deliberate combination of coordination polymers and hydrogen bonds in a supramolecular design strategy for inorganic/organic hybrid networks [J].