Vanadium-molybdenum phosphates supported by TiO2-anatase as new catalysts for selective oxidation of ethane to acetic acid

被引：42

作者：

Roy, M

GubelmannBonneau, M

Ponceblanc, H

Volta, JC

机构：

[1] INST RECH CATALYSE, CNRS, F-69626 VILLEURBANNE, FRANCE

[2] RHONE POULENC RECH, CTR AUBERVILLIERS, F-93309 AUBERVILLIERS, FRANCE

来源：

CATALYSIS LETTERS | 1996年 / 42卷 / 1-2期

关键词：

ethane oxidation; acetic acid; vanadium-molybdenum phosphates; TiO2-anatase;

D O I：

10.1007/BF00814472

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dispersion of vanadium and molybdenum phosphates on titanium oxide (anatase) below the monolayer gives good catalysts for direct oxidation of ethane to acetic acid. By comparison with the dispersion of only vanadium phosphate, the higher selectivity to acetic acid for vanadium and molybdenum phosphates has been explained by an interaction between molybdenum and vanadium as it can be deduced from electron spin resonance and laser Raman spectroscopy studies.

引用

页码：93 / 97

页数：5

共 25 条

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AGUERO A, 1988, HETERGENEOUS CATALYS, V20, P353

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