The coordination and transformation of arene rings by transition metal carbonyl cluster complexes

被引：24

作者：

Brait, S

Deabate, S

Knox, SAR

Sappa, E

机构：

[1] Univ Piemonte Orientale Amedeo Avogadro, Dipartimento Sci & Tecnol Avanzate, I-15100 Alessandria, Italy

[2] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

[3] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

JOURNAL OF CLUSTER SCIENCE | 2001年 / 12卷 / 01期

关键词：

transition metal clusters; benzyne ligands; reactivity; cluster-surface analogy; hydrogenation catalysis (homogeneous; solid-gas; heterogeneous);

D O I：

10.1023/A:1016627113620

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne land, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.

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收藏

页码：139 / 173

页数：35

相关论文

共 221 条

[1] CLUSTER CHEMISTRY .88. REACTIONS BETWEEN RU5(MU(5)-C2PPH2)(MU-PPH2)(CO)13 AND THIOLS - FORMATION AND X-RAY STRUCTURES OF RU5 CLUSTERS CONTAINING C2H, C2PPH2 AND CCH(PPH2) LIGANDS [J].

ADAMS, CJ ;

BRUCE, MI ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 452 (1-2) :121-142

[2] Cycle-addition of buta-1,3-dene to cluster-bound dicarbon:: X-ray structure of Ru5(μ3-C6H6)(μ3-SMe)2(μ-PPh2)2(CO)10 [J].

Adams, CJ ;

Bruce, MI ;

Skelton, BW ;

White, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 573 (1-2) :134-138

[3] DI(BENZENE)HEXARUTHENIUMCARBIDOUNDECACARBONYL, RU6(C)(CO)11(ETA-6-C6H6)2, A NEW ISOMER - THE LARGEST MOLECULAR SANDWICH COMPOUND [J].

ADAMS, RD ;

WU, WG .

POLYHEDRON, 1992, 11 (16) :2123-2124

[4] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A LAYER-SEGREGATED PLATINUM RUTHENIUM CLUSTER COMPLEX THAT EXHIBITS SELECTIVE COORDINATION AND A HIGH-ACTIVITY FOR THE CATALYTIC-HYDROGENATION OF DIPHENYLACETYLENE [J].

ADAMS, RD ;

LI, ZY ;

SWEPSTON, P ;

WU, WG ;

YAMAMOTO, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10657-10658

[5] CATALYTIC-HYDROGENATION OF DIPHENYLACETYLENE BY A LAYER-SEGREGATED PLATINUM-RUTHENIUM CLUSTER COMPLEX [J].

ADAMS, RD ;

BARNARD, TS ;

LI, ZY ;

WU, WG ;

YAMAMOTO, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9103-9113

[6] CLEAVAGE OF ARYL CARBON-SULFUR BONDS BY A TRINUCLEAR CLUSTER - THE REACTION OF ALKYL PHENYL SULFIDES WITH OS3(CO)12 [J].

ADAMS, RD ;

KATAHIRA, DA ;

YANG, LW .

ORGANOMETALLICS, 1982, 1 (02) :235-239

[7]

ALBANESI G, 1986, GAZZ CHIM ITAL, V116, P385

[8] Solid-gas hydrogenation of hex-3-yne and 1,4-cyclohexadiene in the presence of Ru3(CO)9(μ-H)(μ-PPH2), Ru3(CO)10(μ-H)(μ-PPh2), Ru3(CO)7(μ-PPh2)2(C6H4) and Ru4(CO)11(μ4-PPh)(C6H4) deposited on pyrex glass, silica and alumina [J].

Allasia, C ;

Castiglioni, M ;

Giordano, R ;

Sappa, E ;

Verre, F .

JOURNAL OF CLUSTER SCIENCE, 2000, 11 (04) :493-509

[9]

[Anonymous], COMPREHENSIVE ORGANO

[10]

[Anonymous], 1974, ORGANIC CHEM NICKEL

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