Spontaneous polymerization of acrylamide in glycerol

被引：7

作者：

Bol'shakov, A. I. ^{[1
]}

Kiryukhin, D. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Moscow 142432, Russia

来源：

POLYMER SCIENCE SERIES A | 2007年 / 49卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0965545X07090039

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The spontaneous polymerization of acrylamide in glycerol in the range of 250-350 degrees C has been first observed and investigated. It has been shown that the polymerization proceeds during dissolution of acrylamide in glycerol and leads to formation of gel globules in which the growth of polymer chains takes place. The reaction occurs without termination of kinetic chains in the living polymerization mode. The effective chain transfer at a low concentration of active centers ensures a high yield of the polymer.

引用

页码：975 / 980

页数：6

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