Mechanochemical effects on the precursor formation and microwave dielectric characteristics of MgTiO3

被引:33
作者
Baek, JG [1 ]
Isobe, T [1 ]
Senna, M [1 ]
机构
[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT APPL CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN
关键词
mechanochemical effect; Mg-O-Ti complex; precursor; MgTiO3; oxides; microwave dielectric properties;
D O I
10.1016/S0167-2738(96)00387-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mechanochemical effects on the formation of Mg-O-Ti complex and microwave dielectric properties of MgTiO3 oxides were studied using several different starting materials. Single phase MgTiO3 powder was obtained after heating (900 degrees C, 2 h) the mechanically activated precursor from a mixture of two unitary-powders, magnesium hydroxide and anatase (MP). Formation of MgTiO3 on subsequent thermal treatment was significantly accelerated by incipient mechanochemical interaction. The Q value of the ceramics sintered at 1350 degrees C for 2 h from MP was higher than those of three other ceramics due to the uniformity of the microstructure and phase.
引用
收藏
页码:269 / 279
页数:11
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