Triple-decker [Cp*Fe(C8H6)Fe(C8H7)]

被引：5

作者：

AlvarezLarena, A

Brianso, JL

Piniella, JF

Farran, J

Manriquez, JM

Chavez, I

Oelckers, B

Molins, E

Miravitlles, C

机构：

[1] CTR INVEST MINERAS & MET, SANTIAGO, CHILE

[2] UNIV SANTIAGO CHILE, FAC QUIM & BIOL, DEPT CIENCIAS MAT, SANTIAGO, CHILE

[3] PONTIFICIA UNIV CATOLICA VALPARAISO, INST QUIM, VALPARAISO, CHILE

[4] CSIC, INST CIENCIA MAT, BELLATERRA 08193, SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196008037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [2(1,2,3,3a,6a-eta)-1,4-dihydropentalenyl][mu-(1,2,3,3a,6a-eta:3a,4,5,6,6a-eta)pentalene] [1(eta(5))-pentamethylcyclopentadienyl]diiron, [Fe-2(C8H7)(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe-C distances, i.e. a mean value of 2.121 (3) Angstrom for the Fe-C-bridge distances and a mean value of 2.028 (3) Angstrom for the distances from the Fe atoms to all other C atoms. In the terminal pentalene ligand, the C-C and C-Fe distances in the ring bonded to the Fe atom are all similar.

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页码：2754 / 2757

页数：4

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