Side chain Co(I) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

被引：29

作者：

Chadha, Preeti ^{[1
]}

Ragogna, Paul J. ^{[1
]}

机构：

[1] Univ Western Ontario, London, ON N6A 5B7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 18期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

ORGANOMETALLIC BLOCK-COPOLYMERS; RING-OPENING POLYMERIZATION; SOFT MATERIALS; MAIN-CHAIN; THIN-FILMS; COMPLEXES; COBALT; METALLOPOLYMERS; REACTIVITY; PYROLYSIS;

D O I：

10.1039/c1cc11076d

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The synthesis of novel Co(I) polymers featuring CpCo(C4R4) units are reported. The cyclopentadienyl ring on the CpCo(C4R4) unit has been functionalized with acrylate or methacrylate groups. Acrylate derivatives of these compounds were found to polymerize giving rise to the first example of polymers containing neutral, 18 e cobaltoarenocenes in the side chain.

引用

收藏

页码：5301 / 5303

页数：3

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