Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog

被引：99

作者：

Avendano, Carolina ^{[1
]}

Hilfiger, Matthew G. ^{[1
]}

Prosvirin, Andrey ^{[1
]}

Sanders, Codi ^{[1
]}

Stepien, Darryl ^{[1
]}

Dunbar, Kim R. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 38期

关键词：

SINGLE-MOLECULE MAGNETISM; INDUCED SPIN TRANSITION; COBALT-IRON CYANIDE; PHOTOINDUCED MAGNETIZATION; TETRAHEDRAL CORNERS; RE-II; CLUSTER; CROSSOVER; COMPLEXES; BEHAVIOR;

D O I：

10.1021/ja1041513

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)(6)](3-) anion into PB architectures in combination with the Co-II cation. Herein, we report the first example of a photomagnetic PB analog containing Os-III ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering.

引用

页码：13123 / 13125

页数：3

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