A monocarboxylate-bridged diiron(III) μ-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

被引：14

作者：

Jarenmark, Martin ^{[1
]}

Turitsyna, Elena A. ^{[2
]}

Haukka, Matti ^{[3
]}

Shteinman, Albert A. ^{[2
]}

Nordlander, Ebbe ^{[1
]}

机构：

[1] Lund Univ, Ctr Chem & Chem Engn, Inorgan Chem Res Grp, SE-22100 Lund, Sweden

[2] Inst Problems Chem Phys, Chernogolovka 142432, Russia

[3] Univ Joensuu, Dept Chem, FI-80101 Joensuu, Finland

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 10期

基金：

瑞典研究理事会;

关键词：

DISTINCT IRON SITES; C-H BONDS; METHANE MONOOXYGENASE; HYDROXYLATION; ACTIVATION; MANGANESE; LIGANDS; HISTORY; ENZYMES; MODELS;

D O I：

10.1039/c0nj00293c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H(2)IPCPMP) with two equivalents of Fe(ClO(4))(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO(4) (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

引用

页码：2118 / 2121

页数：4

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