Synergetic activation of "silent receptor" sites leading to a new type of inclusion complex:: integration of a 64-membered ring comprising K+ and SO42- ions into a molybdenum oxide-based nanoobject

被引：37

作者：

Müller, A ^{[1
]}

Toma, L ^{[1
]}

Bögge, H ^{[1
]}

Schmidtmann, M ^{[1
]}

Kögerler, P ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Biol, Lehrstuhl Anorgan Chem 1, D-33501 Bielefeld, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 16期

关键词：

D O I：

10.1039/b305447k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new type of inclusion species [(Mo114Mo32O429)-Mo-VI-O-V(H2O)(50)(KSO4)(16)](30-) comprising 16 encapsulated K+ and SO42- ions shows an unusual 64-membered {K(SO4)}(16) ring integrated into a wheel-shaped type nanocluster host; it is formed by a synergetically induced functional complementarity and represents a text-book example of a very complex non-biological material.

引用

页码：2000 / 2001

页数：2

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