Renewable hydrogen by aqueous-phase reforming of glucose

被引：142

作者：

Davda, RR ^{[1
]}

Dumesic, JA ^{[1
]}

机构：

[1] Univ Wisconsin, Madison, WI 53706 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 01期

关键词：

D O I：

10.1039/b310152e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen can be produced from aqueous solutions containing 10 wt% glucose with high selectivities through the combined use of a hydrogenation reactor for conversion of glucose to sorbitol, followed by a reforming reactor for conversion of sorbitol to H-2 and CO2 and then a gas-liquid separator for the removal of high-pressure H-2-rich reformate gas, ready for use in a fuel cell.

引用

页码：36 / 37

页数：2

共 10 条

[1] The molecular basis of zeolite catalysis: A review of theoretical simulations
Bates, SP
Van Santen, RA
[J]. ADVANCES IN CATALYSIS, VOL 42, 1998, 42 : 1 - 114
[2] Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water
Cortright, RD
Davda, RR
Dumesic, JA
[J]. NATURE, 2002, 418 (6901) : 964 - 967
[3] Catalytic reforming of oxygenated hydrocarbons for hydrogen with low levels of carbon monoxide
Davda, RR
Dumesic, JA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (34) : 4068 - 4071
[4] Aqueous-phase reforming of ethylene glycol on silica-supported metal catalysts
Davda, RR
Shabaker, JW
Huber, GW
Cortright, RD
Dumesic, JA
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 43 (01) : 13 - 26
[5] GLUCOSE HYDROGENATION ON PROMOTED RANEY-NICKEL CATALYSTS
GALLEZOT, P
CERINO, PJ
BLANC, B
FLECHE, G
FUERTES, P
[J]. JOURNAL OF CATALYSIS, 1994, 146 (01) : 93 - 102
[6] Catalytic steam reforming of bio-oils for the production of hydrogen: effects of catalyst composition
Garcia, L
French, R
Czernik, S
Chornet, E
[J]. APPLIED CATALYSIS A-GENERAL, 2000, 201 (02) : 225 - 239
[7] Raney Ni-Sn catalyst for H2 production from biomass-derived hydrocarbons
Huber, GW
Shabaker, JW
Dumesic, JA
[J]. SCIENCE, 2003, 300 (5628) : 2075 - 2077
[8] Glucose and fructose decomposition in subcritical and supercritical water: Detailed reaction pathway, mechanisms, and kinetics
Kabyemela, BM
Adschiri, T
Malaluan, RM
Arai, K
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (08) : 2888 - 2895
[9] Aqueous-phase reforming of methanol and ethylene glycol over alumina-supported platinum catalysts
Shabaker, JW
Davda, RR
Huber, GW
Cortright, RD
Dumesic, JA
[J]. JOURNAL OF CATALYSIS, 2003, 215 (02) : 344 - 352
[10] Biotechnology - Enzymatic production of biohydrogen
Woodward, J
Orr, M
Cordray, K
Greenbaum, E
[J]. NATURE, 2000, 405 (6790) : 1014 - 1015

← 1 →