Synthesis and X-ray crystal structure of 1,2-diaminepropane platinum(II) cantharidinate

被引：6

作者：

Wang, YH

Huang, ZX

Wu, C

机构：

[1] FUDAN UNIV,DEPT CHEM,SHANGHAI 200433,PEOPLES R CHINA

[2] FUDAN UNIV,CTR ANAL & MEASUREMENT,SHANGHAI 200433,PEOPLES R CHINA

来源：

POLYHEDRON | 1997年 / 16卷 / 01期

关键词：

platinum complex; cantharidine; synthesis; structure determination;

D O I：

10.1016/0277-5387(96)00253-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1,2-diaminepropane platinum(II) cantharidinate was synthesized by reacting sodium cantharidinate with 1,2-diaminepropane diiodo platinum(II) in aqueous solution. The crystal structure of the platinum complex was determined by X-ray diffraction. The complex is a binuclear molecule, in which each platinum ion is coordinated by two carboxylic oxygen atoms from two different cantharidinates and two amine nitrogen atoms from the same 1,2-diaminepropane molecule. The platinum(II) ion takes a typical square planar configuration. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：57 / 59

页数：3

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