Tunable materials from hydrogen-bonded pseudo block copolymers

被引：129

作者：

Binder, WH

Bernstorff, S

Kluger, C

Petraru, L

Kunz, MJ

机构：

[1] Vienna Univ Technol, Inst Appl Synth Chem, Div Macromol Technol, A-1060 Vienna, Austria

[2] ELETTRA Lab, I-34012 Trieste, Italy

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 23期

关键词：

D O I：

10.1002/adma.200501505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pseudo block copolymers with tunable micro- or macrophase-separated structures are created by introducing multiple hydrogen-bonding groups at the polymer ends (see Figure). The resulting materials are stabilized up to 80 degrees C above the glass-transition temperature (T-g) of the higher-T-g component.

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页码：2824 / +

页数：6

相关论文

共 38 条

[1]

Berl V, 2002, CHEM-EUR J, V8, P1227, DOI 10.1002/1521-3765(20020301)8:5<1227::AID-CHEM1227>3.0.CO

[2]

2-0

[3] Polymeric ordering by H-bonds. Mimicking nature by smart building blocks [J].

Binder, WH .

MONATSHEFTE FUR CHEMIE, 2005, 136 (01) :1-19

[4] Combining ring-opening metathesis polymerization (ROMP) with sharpless-type "click" reactions: An easy method for the preparation of side chain functionalized poly(oxynorbornenes) [J].

Binder, WH ;

Kluger, C .

MACROMOLECULES, 2004, 37 (25) :9321-9330

[5] Synthesis and analysis of telechelic polyisobutylenes for hydrogen-bonded supramolecular pseudo-block copolymers [J].

Binder, WH ;

Kunz, MJ ;

Kluger, C ;

Hayn, G ;

Saf, R .

MACROMOLECULES, 2004, 37 (05) :1749-1759

[6] Supramolecular poly(ether ketone)-polyisobutylene pseudo-block copolymers [J].

Binder, WH ;

Kunz, MJ ;

Ingolic, E .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (01) :162-172

[7] Supramolecular polymers [J].

Brunsveld, L ;

Folmer, BJB ;

Meijer, EW ;

Sijbesma, RP .

CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097

[8] Self-sorting in polymers [J].

Burd, C ;

Weck, M .

MACROMOLECULES, 2005, 38 (17) :7225-7230

[9] HYDROGEN-BONDING AND MOLECULAR RECOGNITION - SYNTHETIC, COMPLEXATION, AND STRUCTURAL STUDIES ON BARBITURATE BINDING TO AN ARTIFICIAL RECEPTOR [J].

CHANG, SK ;

VANENGEN, D ;

FAN, E ;

HAMILTON, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7640-7645

[10] MOLECULAR RECOGNITION OF BIOLOGICALLY INTERESTING SUBSTRATES - SYNTHESIS OF AN ARTIFICIAL RECEPTOR FOR BARBITURATES EMPLOYING 6 HYDROGEN-BONDS [J].

CHANG, SK ;

HAMILTON, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (04) :1318-1319

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