In situ ATRP-Mediated hierarchical formation of giant amphiphile bionanoreactors

被引:84
作者
Le Droumaguet, Benjamin [1 ]
Velonia, Kelly [1 ]
机构
[1] Univ Geneva, Dept Chem, CH-1211 Geneva, Switzerland
关键词
bioconjugates; hierarchical assembly; nanostructures; polymerization;
D O I
10.1002/anie.200801007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Functional giants: Amphiphilic bioconjugates can be synthesized in situ by grafting polystyrene from a protein (see scheme). The resulting giant amphiphiles display low polydispersities and the characteristic aggregation properties of amphiphilic biomacromolecules. A second, catalytically active guest protein can also be included within the superstructures. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6263 / 6266
页数:4
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