Energy transfer within perylene-terrylene dendrimers evidenced by polychromatic transient absorption measurements

被引：30

作者：

Jordens, Sven ^{[1
]}

De Belder, Gino ^{[1
]}

Lor, Marc ^{[1
]}

Schweitzer, Gerd ^{[1
]}

Van der Auweraer, Mark ^{[1
]}

Weil, Tanja ^{[2
]}

Reuther, Erik ^{[2
]}

Muellen, Klaus ^{[2
]}

De Schryver, Frans C. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200 F, B-3001 Heverlee, Belgium

[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2003年 / 2卷 / 03期

关键词：

D O I：

10.1039/b210261g

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The time dependent spectral properties of a first and a second generation dendrimer with peryleneimide chromophores at the rim and a terrylenediimide chromophore in the core were investigated by time resolved polychromatic transient absorption measurements. The obtained results of the dendritic structures were compared with those of three model compounds. In the perylene-terryiene dendrimers a very fast energy transfer process was observed. Besides energy transfer singlet-singlet annihilation could be observed. It could be concluded that competition between the rates of energy transfer and of singlet-singlet annihilation is dependent on the dendrimer generation.

引用

页码：177 / 186

页数：10

共 43 条

[1] Light harvesting and energy transfer in laser-dye-labeled poly(aryl ether) dendrimers [J].

Adronov, A ;

Gilat, SL ;

Fréchet, JMJ ;

Ohta, K ;

Neuwahl, FVR ;

Fleming, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (06) :1175-1185

[2] GLOBULAR CARBOHYDRATE MACROMOLECULE SUGAR BALLS .1. SYNTHESIS OF NOVEL SUGAR-PERSUBSTITUTED POLY(AMIDO AMINE) DENDRIMERS [J].

AOI, K ;

ITOH, K ;

OKADA, M .

MACROMOLECULES, 1995, 28 (15) :5391-5393

[3] Functional cascade molecules [J].

Archut, A ;

Vögtle, F .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :233-240

[4] Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns [J].

Balzani, V ;

Campagna, S ;

Denti, G ;

Juris, A ;

Serroni, S ;

Venturi, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) :26-34

[5]

Choi MS, 2001, ANGEW CHEM INT EDIT, V40, P3194, DOI 10.1002/1521-3773(20010903)40:17<3194::AID-ANIE3194>3.0.CO

[6]

2-5

[7] Femtosecond fluorescence upconversion study of rigid dendrimers containing peryleneimide chromophores at the rim [J].

De Belder, G ;

Jordens, S ;

Lor, M ;

Schweitzer, G ;

De, R ;

Weil, T ;

Herrmann, A ;

Wiesler, UK ;

Müllen, K ;

De Schryver, FC .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 145 (1-2) :61-70

[8]

De Belder G, 2001, CHEMPHYSCHEM, V2, P49, DOI 10.1002/1439-7641(20010119)2:1<49::AID-CPHC49>3.0.CO

[9]

2-6

[10] Energy transfer in dendritic macromolecules: Molecular size effects and the role of an energy gradient [J].

Devadoss, C ;

Bharathi, P ;

Moore, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (40) :9635-9644

← 1 2 3 4 5 →