Influence of iron additions on structure and properties of amorphous Zr65Al7.5CU17.5Ni10

被引:10
作者
Mattern, N [1 ]
Roth, S [1 ]
Bauer, HD [1 ]
Henninger, G [1 ]
Eckert, J [1 ]
机构
[1] Inst Festkorper & Werkstofforsch Dresden, D-01171 Dresden, Germany
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2001年 / 304卷 / 1-2期
关键词
metallic glass; structure; crystallization;
D O I
10.1016/S0921-5093(00)01439-8
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Amorphous (Zr65Al7.5Cu17.5N10)(100-x)Fe-x alloys (0 less than or equal to x less than or equal to 20) prepared by rapid quenching were investigated by DSC, X-ray diffraction, TEM and magnetization measurement. The short-range order of the bulk glass is found to be similar to that of amorphous binary Zr66M33 alloys (M = Cu, Ni, Fe). For x = 20 at.% Fe a small contribution of magnetic clusters is observed. The amorphous Zr65Al7.5Cu17.5Ni10 alloy crystallizes eutectically into CuZr2 and Zr6NiAl2 Fe addition leads to a changed crystallization sequence. A metastable f.c.c. phase (NiTi2-type) is formed for x greater than or equal to 1 at.% iron. With increasing iron content the metastable cubic phase becomes stabilized and the microstructure in the first stage of crystallization changes into a nanocrystalline state. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:311 / 314
页数:4
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