Pinacolization and reduction of aromatic carbonyls with aluminium-KOH

被引：30

作者：

Khurana, JM ^{[1
]}

Sehgal, A ^{[1
]}

Gogia, A ^{[1
]}

Manian, A ^{[1
]}

Maikap, GC ^{[1
]}

机构：

[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 17期

关键词：

D O I：

10.1039/p19960002213

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and rapid procedure for the pinacolization of aromatic aldehydes and reduction of hindered ketones with inexpensive aluminium and KOH in methanol at ambient temperature is reported, The pinacolization and reduction are proposed to be proceeding via single electron transfer from aluminium.

引用

页码：2213 / 2215

页数：3

共 25 条

[1] THE OXIDATION POTENTIALS OF ALDEHYDES AND KETONES [J].