The Next Chapter in MOF Pillaring Strategies: Trigonal Heterofunctional Ligands To Access Targeted High-Connected Three Dimensional Nets, Isoreticular Platforms

被引：161

作者：

Eubank, Jarrod F. ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Hight, Matthew R. ^{[1
]}

Bousquet, Till ^{[1
]}

Kravtsov, Victor Ch. ^{[2
]}

Eddaoudi, Mohamed ^{[1
,3
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova

[3] 4700 King Abdullah Univ Sci & Technol, KAUST Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 44期

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH H-2 ADSORPTION; BUILDING-BLOCKS; CRYSTAL-STRUCTURES; KAGOME LATTICE; COORDINATION; DESIGN; PRINCIPLES; EXAMPLES; DATABASE;

D O I：

10.1021/ja203898s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated Trigonal heterofunctional ligands, in this case isophthalic acid cores functionalized at the 5-position with N-donor (e.g., pyridyl- or triazolyl-type) moieties, are designed and utilized to pillar pretargeted two-dimensional layers (supermolecular building layers, SBLs). These SBLs, based on edge transitive Kagome and square lattices, are cross-linked into predicted three-dimensional MOFs with tunable large cavities, resulting in isoreticular platforms.

引用

页码：17532 / 17535

页数：4

共 28 条

[1] Coordination polymers from calixarene-like [Cu2(dicarboxylate)2]4 building blocks:: Structural diversity via atropisomerism [J].