Odd-Even Effect in the Synthesis of Mesoporous Silicate Molecular Sieves in the Presence of Alkyl Cetyl Dimethyl Ammonium Bromide

被引：8

作者：

Karra, Vanaja R.

Moudrakovski, Igor L.

Sayari, Abdelhamid ^{[1
]}

机构：

[1] Univ Laval, Dept Chem Engn, Ste Foy, PQ G1K 7P4, Canada

来源：

JOURNAL OF POROUS MATERIALS | 1996年 / 3卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

odd-even effect; MCM-41; mesoporous silicate; surfactant organization;

D O I：

10.1007/BF01186036

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

New quaternary ammonium salts with the formula, (C16H33)(CnH2+1)(CH3)(2)N+Br- (n = 1 to 12) have been synthesized and used as templates to prepare crystalline mesoporous molecular sieves. The effect of the CnH2+1 chain length on the nature of the obtained product and its d-distance has been investigated. A correlation between the nature of the obtained phases and the conformation of the carbon chain of the occluded surfactant was revealed by C-13 CP MAS NMR.

引用

页码：77 / 82

页数：6

共 26 条

[1] MOISTURE ABSORPTION CHARACTERISTICS OF ORGANOSILOXANE SELF-ASSEMBLED MONOLAYERS
ANGST, DL
SIMMONS, GW
[J]. LANGMUIR, 1991, 7 (10) : 2236 - 2242
[2] MOLECULAR OR SUPRAMOLECULAR TEMPLATING - DEFINING THE ROLE OF SURFACTANT CHEMISTRY IN THE FORMATION OF MICROPOROUS AND MESOPOROUS MOLECULAR-SIEVES
BECK, JS
VARTULI, JC
KENNEDY, GJ
KRESGE, CT
ROTH, WJ
SCHRAMM, SE
[J]. CHEMISTRY OF MATERIALS, 1994, 6 (10) : 1816 - 1821
[3] BECK JS, 1992, AM CHEM SOC, V114, P10834, DOI DOI 10.1021/JA00053A020
[4] Chandrasekhar S., 1980, LIQ CRYST
[5] STUDIES ON MESOPOROUS MATERIALS .1. SYNTHESIS AND CHARACTERIZATION OF MCM-41
CHEN, CY
LI, HX
DAVIS, ME
[J]. MICROPOROUS MATERIALS, 1993, 2 (01): : 17 - 26
[6] OBSERVATIONS IN SOLID POLYETHYLENES BY C-13 NUCLEAR MAGNETIC-RESONANCE WITH MAGIC ANGLE SAMPLE SPINNING
EARL, WL
VANDERHART, DL
[J]. MACROMOLECULES, 1979, 12 (04) : 762 - 767
[7] COOPERATIVE ORGANIZATION OF INORGANIC-SURFACTANT AND BIOMIMETIC ASSEMBLIES
FIROUZI, A
KUMAR, D
BULL, LM
BESIER, T
SIEGER, P
HUO, Q
WALKER, SA
ZASADZINSKI, JA
GLINKA, C
NICOL, J
MARGOLESE, D
STUCKY, GD
CHMELKA, BF
[J]. SCIENCE, 1995, 267 (5201) : 1138 - 1143
[8] FROBA M, 1995, MATER RES SOC SYMP P, V371, P99
[9] SOLID-STATE NMR-STUDIES OF SELF-ASSEMBLED MONOLAYERS
GAO, W
REVEN, L
[J]. LANGMUIR, 1995, 11 (06) : 1860 - 1863
[10] GENERALIZED SYNTHESIS OF PERIODIC SURFACTANT INORGANIC COMPOSITE-MATERIALS
HUO, QS
MARGOLESE, DI
CIESLA, U
FENG, PY
GIER, TE
SIEGER, P
LEON, R
PETROFF, PM
SCHUTH, F
STUCKY, GD
[J]. NATURE, 1994, 368 (6469) : 317 - 321

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