Metal-catalysed multiple boration of ketimines

被引：28

作者：

Cameron, TM

Baker, RT

Westcott, SA

机构：

[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA

[2] Mt Allison Univ, Dept Chem, Sackville, NB E4L 1G8, Canada

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a805792c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-catalysed addition of B(2)cat(2)' (cat' = 4-Bu-t-1,2-O2C6H3) to ketimines affords N-borylenamines and HBcat'. Analogous catalysed reactions of ketimines with HBcat' in tetrahydrofuran afford multiply berated products, providing the first examples of metal-catalysed hydroboration of enamines.

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收藏

页码：2395 / 2396

页数：2

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