High-yield synthesis and single-crystal X-ray structure of a plutonium(III) aquo complex:: [Pu(H2O)9][CF3SO3]3

被引：62

作者：

Matonic, JH ^{[1
]}

Scott, BL ^{[1
]}

Neu, MP ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 12期

关键词：

D O I：

10.1021/ic015509p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aquo complex of Pu(III) is 9-coordinate with an ideal tricapped trigonal-prismatic geometry. The cation was crystallized as the triflate salt in quantitative yield from dissolution of Pu metal in triflic acid. Structural comparisons with analogous lanthanide aquo complexes are presented.

引用

页码：2638 / 2639

页数：2

共 18 条

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