Characterization of humic-like substances in airborne particulate matter by capillary electrophoresis

被引:31
作者
Havers, N
Burba, P
Klockow, D
Klockow-Beck, A
机构
[1] Inst Spektrochem & Angew Spekt, D-44013 Dortmund, Germany
[2] RW Johnson Pharmaceut Res Inst, CH-8205 Schaffhausen, Switzerland
关键词
capillary electrophoresis; airborne particles; humic-like substances;
D O I
10.1007/BF02467443
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A considerable fraction of the refractory organic carbon in airborne particulate matter is to be attributed to humic-like substances (HULIS). Such atmospheric HULIS isolated from different air dust samples by a microscale extraction procedure were characterized by capillary electrophoresis (CE). For fractionation of HULIS the working conditions of the CE system were optimized using a berate buffer (pH 8.2), polyacrylamide (PAA) coated, fused-silica capillary and polyethylene glycol as sieving modifier. Using CE under optimized conditions, HULIS produced electropherograms showing well resolved and reproducible signals.
引用
收藏
页码:619 / 624
页数:6
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