A bimetallic bis-pentalene sandwich complex:: Synthesis and structure of Mo2[C8H4(1,4-SiPri3)2]2

被引：34

作者：

Kuchta, MC ^{[1
]}

Cloke, FGN ^{[1
]}

Hitchcock, PB ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 10期

关键词：

D O I：

10.1021/om980056q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between K-2[C8H4(1,4-SiPr3i)(2)] and Mo-2(OAc)(4) yields Mo-2[C8H4(1,4-SiPr3i)(2)](2), the first example ofa bimetallic bis-pentalene sandwich complex to be structurally characterized by X-ray diffraction. Structural data show that the carbon frameworks of the two pentalene ligands are eclipsed and effectively planar with fold angles of ca. 2 degrees and 3 degrees while the SiPr3i groups are staggered the Mo-Mo distance is 2.340(1) Angstrom.

引用

页码：1934 / 1936

页数：3

共 51 条

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