The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions

被引：63

作者：

Choi, Doo Seong

Kim, Dong Hyun

Shin, Ueon Sang

Deshmukh, Ravindra R.

Lee, Sang-Gi

Song, Choong Eui ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Inst Basic Sci, Suwon 440746, South Korea

[2] Ewha Womans Univ, Dept Chem, Div Nanosci BK21, Seoul 120750, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 33期

关键词：

D O I：

10.1039/b708044a

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Imidazolium ionic liquids (ILs) exhibited a dramatic acceleration effect on the electron transfer from metal complexes such as (C5Me5)(2)Fe(II) and (C5Me5)(2)Co(II) to the oxygen molecule; this acceleration effect can be ascribed to the stabilization of the oxygen radical anions by coordinating with the acidic C2-H of imidazolium ILs.

引用

收藏

页码：3467 / 3469

页数：3

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