Compounds that contract on heating

被引：266

作者：

Sleight, AW ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 12期

关键词：

D O I：

10.1021/ic980253h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various mechanisms to explain negative thermal expansion in oxides are presented. Our search for compounds having this unusual property has focused on the mechanism based on transverse thermal motion of oxygen in M-O-M Linkages. Such a mechanism can give strong negative thermal expansion over broad temperature ranges. Examples of compounds where this mechanism operates to give negative thermal expansion are ZrW2O8, the SC2W3O12 family, NbOPO4, AlPO4-17, and faujasite SiO2.

引用

页码：2854 / 2860

页数：7

共 29 条

[1]

AMOS T, UNPUB

[2]

[Anonymous], UNPUB

[3]

ATTFIELD M, UNPUB CHEM MAT

[4]

ATTFIELD MP, IN PRESS CHEM COMMUN

[5] CRYSTALLINE NETWORKS WITH UNUSUAL PREDICTED MECHANICAL AND THERMAL-PROPERTIES [J].

BAUGHMAN, RH ;

GALVAO, DS .

NATURE, 1993, 365 (6448) :735-737

[6] CONDENSED PHASE RELATIONS IN SYSTEMS ZRO2-WO2-WO3 AND HFO2-WO2-WO3 [J].

CHANG, LLY ;

SCROGER, MG ;

PHILLIPS, B .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (04) :211-&

[7]

CLOSMANN C, IN PRESS J SOLID STA

[8] Rigid unit modes in framework silicates [J].

Dove, MT ;

Heine, V ;

Hammonds, KD .

MINERALOGICAL MAGAZINE, 1995, 59 (397) :629-639

[9] Compressibility, phase transitions, and oxygen migration in zirconium tungstate, ZrW2O8 [J].

Evans, JSO ;

Hu, Z ;

Jorgensen, JD ;

Argyriou, DN ;

Short, S ;

Sleight, AW .

SCIENCE, 1997, 275 (5296) :61-65

[10] Negative thermal expansion in ZrW2O8 and HfW2O8 [J].

Evans, JSO ;

Mary, TA ;

Vogt, T ;

Subramanian, MA ;

Sleight, AW .

CHEMISTRY OF MATERIALS, 1996, 8 (12) :2809-2823

← 1 2 3 →