The first structural characterization of a [2.2]PHANEPHOS -: Transition-metal complex:: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl2]

被引：24

作者：

Dyer, PW

Dyson, PJ ^{[1
]}

James, SL

Martin, CM

Suman, P

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Ctr Chem Synth, London SW7 2AY, England

[2] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 20期

关键词：

D O I：

10.1021/om980416+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.

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页码：4344 / 4346

页数：3

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