Ionic conductivity studies of plasticized poly(vinyl chloride) polymer electrolytes

被引:255
作者
Ramesh, S
Arof, AK [1 ]
机构
[1] Univ Malaya, Ctr Fdn Studies Sci, Dept Phys, Kuala Lumpur 50603, Malaysia
[2] Univ Malaya, Inst Postgrad Studies & Res, Kuala Lumpur 50603, Malaysia
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2001年 / 85卷 / 01期
关键词
PVC; ionic conductivity; plasticizers;
D O I
10.1016/S0921-5107(01)00555-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The ionic conductivity studies have been conducted for poly (vinyl chloride) polymer electrolytes (PVC:LiCF3SO3:LiBF4:PC:EC) over a wide frequency regime. It was found that the addition of plasticizers significantly improved the ionic conductivity. The dielectric data were analyzed using complex impedance Z*, complex admittance A*, complex permittivity epsilon* and complex electric modulus M* of the sample with the highest ionic conductivity at various temperatures. The conductivity-temperature data obeys the classical Arrhenius relationship. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:11 / 15
页数:5
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