Nonlinear wavelet compression of ion mobility spectra from ion mobility spectrometers mounted in an unmanned aerial vehicle

被引:12
作者
Cao, L
Harrington, PD [1 ]
Harden, CS
McHugh, VM
Thomas, MA
机构
[1] Ohio Univ, Clippinger Labs, Dept Chem & Biochem, Ctr Intelligent Chem Instrumentat, Athens, OH 45701 USA
[2] USA, Edgewood Chem Biol Ctr, Aberdeen Proving Ground, MD 21010 USA
[3] Smith Detect, Watford WD2 2BW, Herts, England
关键词
D O I
10.1021/ac0351466
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Linear and nonlinear wavelet compression of ion mobility spectrometry (IMS) data are compared and evaluated. IMS provides low detection limits and rapid response for many compounds. Nonlinear wavelet compression of ion mobility spectra reduced the data to 4-5% of its original size, while eliminating artifacts in the reconstructed spectra that occur with linear compression, and the root-mean-square reconstruction error was 0.17-0.20% of the maximum intensity of the uncompressed spectra. Furthermore, nonlinear wavelet compression precisely preserves the peak location (i.e., drift time). Small variations in peak location may occur in the reconstructed spectra that were linearly compressed. A method was developed and evaluated for optimizing the compression. The compression method was evaluated with in-flight data recorded from ion mobility spectrometers mounted in an unmanned aerial vehicle (UAV). Plumes of dimethyl methylphosphonate were disseminated for interrogation by the UAV-mounted IMS system. The daublet 8 wavelet filter exhibited the best performance for these evaluations.
引用
收藏
页码:1069 / 1077
页数:9
相关论文
共 27 条
  • [1] Using wavelets transform in the analysis of electrochemical noise data
    Aballe, A
    Bethencourt, M
    Botana, FJ
    Marcos, M
    [J]. ELECTROCHIMICA ACTA, 1999, 44 (26) : 4805 - 4816
  • [2] ABE S, 1995, ZOOL STUD, V34, P121
  • [3] An introduction to wavelet transforms for chemometricians: A time-frequency approach
    Alsberg, BK
    Woodward, AM
    Kell, DB
    [J]. CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1997, 37 (02) : 215 - 239
  • [4] Oscillatory brain dynamics, wavelet analysis, and cognition
    Basar, E
    Demiralp, T
    Schürmann, M
    Basar-Eroglu, C
    Ademoglu, A
    [J]. BRAIN AND LANGUAGE, 1999, 66 (01) : 146 - 183
  • [5] Bruce A, 1996, IEEE SPECTRUM, V33, P12
  • [6] Wavelet transform preprocessing for temperature constrained cascade correlation neural networks
    Cai, C
    Harrington, PD
    [J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1999, 39 (05): : 874 - 880
  • [7] Two-dimensional Fourier compression
    Cai, CS
    Harrington, PD
    Davis, DM
    [J]. ANALYTICAL CHEMISTRY, 1997, 69 (20) : 4249 - 4255
  • [8] Spike removal and denoising of Raman spectra by wavelet transform methods
    Ehrentreich, F
    Sümmchen, L
    [J]. ANALYTICAL CHEMISTRY, 2001, 73 (17) : 4364 - 4373
  • [9] A critical review of ion mobility spectrometry for the detection of explosives and explosive related compounds
    Ewing, RG
    Atkinson, DA
    Eiceman, GA
    Ewing, GJ
    [J]. TALANTA, 2001, 54 (03) : 515 - 529
  • [10] Recovery of variable loadings and eigenvalues directly from Fourier compressed ion mobility spectra
    Harrington, PD
    Hu, LJ
    [J]. APPLIED SPECTROSCOPY, 1998, 52 (10) : 1328 - 1338