Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials

被引：7

作者：

Wragg, D ^{[1
]}

Morris, RE ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2001年 / 11卷 / 02期

关键词：

D O I：

10.1039/b006176j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition metals (Cu, Mn and Co) have been substituted for gallium in an azamacrocycle-containing gallium phosphate inorganic-organic hybrid material (GaPO4)(2)(OH)F-2. Ga(C10N4H24). The substitution of the gallium by copper and manganese occurs at the octahedral site that is at the centre of the azamacrocycle complex. The effect of this substitution on the structure of the materials has been studied using Rietveld refinement against synchrotron X-ray powder diffraction data and electron spin resonance spectroscopy.

引用

页码：513 / 517

页数：5

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