Chelation-controlled reduction of α- and β-oxygenated ketones with lithium tri-n-butylborohydride.

被引：19

作者：

Faucher, AM ^{[1
]}

Brochu, C ^{[1
]}

Landry, SR ^{[1
]}

Duchesne, I ^{[1
]}

Hantos, S ^{[1
]}

Roy, A ^{[1
]}

Myles, A ^{[1
]}

Legault, C ^{[1
]}

机构：

[1] Boehringer Ingelheim Canada Ltd, Biomega Res Div, Laval, PQ H7S 2G5, Canada

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 46期

关键词：

boron and compounds; lithium and compounds; reduction; chelation;

D O I：

10.1016/S0040-4039(98)01883-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lithium tri-n-butyl borohydride showed high selectivity in the reduction of alpha- and beta-oxygenated ketones, giving a preponderance of the chelation controlled products. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8425 / 8428

页数：4

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