Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol)

被引:133
作者
Aihara, H [1 ]
Matsuo, T [1 ]
Kawaguchi, H [1 ]
机构
[1] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448585, Japan
关键词
D O I
10.1039/b305745c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and characterization of titanium complexes of the aryloxido-functionalized N-heterocyclic carbene ligand (L) is reported, in which the tridentate L ligand meridionally coordinates to the metal center.
引用
收藏
页码:2204 / 2205
页数:2
相关论文
共 28 条
[1]  
ABEMETHY CD, 2003, J AM CHEM SOC, V125, P1128
[2]   Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper [J].
Arnold, PL ;
Scarisbrick, AC ;
Blake, AJ ;
Wilson, C .
CHEMICAL COMMUNICATIONS, 2001, (22) :2340-2341
[3]   Synthesis of a transient tropylidene substituted N-heterocyclic carbene (tropNHC):: rearrangement and formation of its gold complex [J].
Böhler, C ;
Stein, D ;
Donati, N ;
Grützmacher, H .
NEW JOURNAL OF CHEMISTRY, 2002, 26 (10) :1291-1295
[4]   Stable carbenes [J].
Bourissou, D ;
Guerret, O ;
Gabbaï, FP ;
Bertrand, G .
CHEMICAL REVIEWS, 2000, 100 (01) :39-91
[5]  
Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO
[6]  
2-3
[7]   TRANSITION METAL-CARBENE COMPLEXES [J].
CARDIN, DJ ;
CETINKAY.B ;
LAPPERT, MF .
CHEMICAL REVIEWS, 1972, 72 (05) :545-+
[8]   Synthesis and structures of 1,3,1′,3′-tetrabenzyl-2,2′-biimidazolidinylidenes (electron-rich alkenes), their aminal intermediates and their degradation products [J].
Çetinkaya, B ;
Çetinkaya, E ;
Chamizo, JA ;
Hitchcock, PB ;
Jasim, HA ;
Küçükbay, H ;
Lappert, MF .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (13) :2047-2054
[9]   Nine-membered titanacyclic complexes based on an ethylene-bridged bis(phenolato) ligand: Synthesis, structure, and olefin polymerization activity [J].
Fokken, S ;
Spaniol, TP ;
Okuda, J ;
Sernetz, FG ;
Mulhaupt, R .
ORGANOMETALLICS, 1997, 16 (20) :4240-4242
[10]   Tridentate carbene CCC and CNC pincer palladium(II) complexes: Structure, fluxionality, and catalytic activity [J].
Grundemann, S ;
Albrecht, M ;
Loch, JA ;
Faller, JW ;
Crabtree, RH .
ORGANOMETALLICS, 2001, 20 (25) :5485-5488