Actinyl peroxide nanospheres

被引：229

作者：

Burns, PC

Kubatko, KA

Sigmon, G

Fryer, BJ

Gagnon, JE

Antonio, MR

Soderholm, L

机构：

[1] Univ Notre Dame, Dept Civil Engn & Geol Sci, Notre Dame, IN 46556 USA

[2] Univ Windsor, Great Lakes Inst Environm Res, Windsor, ON N9B 3P4, Canada

[3] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 14期

关键词：

actinides; peroxides; polyoxometalates; self-assembly; uranium;

D O I：

10.1002/anie.200462445

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Waste not: Actinyl nanospheres self-assembled from alkaline solutions have been shown to be composed of 24, 28, and 32 actinyl peroxide polyhedra (for example, see picture of the uranyl peroxide polyhedra (U-28)). The nanospheres represent a new class of polyoxometalates, and their formation in nuclear waste may have an impact on the mobility of actinides in the environment. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2135 / 2139

页数：5

共 24 条

[1] Nanoparticles in the environment [J].