Structure and solvation in ionic liquids

被引：304

作者：

Hardacre, Christopher ^{[1
]}

Holbrey, John D.

Nieuwenhuyzen, Mark

Youngs, Tristan G. A.

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland

[2] Queens Univ Belfast, Sch Math & Phys, Belfast BT9 5AG, Antrim, North Ireland

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 11期

关键词：

D O I：

10.1021/ar700068x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Account describes experimental data used to understand the structure of ionic liquids and solute-solvent interactions of both molecular solutes and dissolved metal complexes. In general, the structures of the ionic liquids determined from experimental data show good agreement with both simulated structures and solid-state structures. For all ionic liquids studied, strong charge ordering is found leading to long-range order even in the presence of a solute. For dissolved metal complexes, the ionic liquid is not innocent and a clear dependence on the speciation is observed with variations in both the cation and anion.

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页码：1146 / 1155

页数：10

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