Influence of the extraction methods to remove organic templates from Al-MCM-41 molecular sieves

被引:23
作者
Gomes, WA [1 ]
Cardoso, LAM [1 ]
Gonzaga, ARE [1 ]
Aguiar, LG [1 ]
Andrade, HMC [1 ]
机构
[1] Univ Fed Bahia, Inst Quim, BR-40170290 Salvador, BA, Brazil
关键词
Al-MCM-41; template; extraction; supercritical fluid extraction;
D O I
10.1016/j.matchemphys.2005.02.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influence of template extraction methods on the structure and physico-chemical properties of Al-MCM-41 molecular sieves has been investigated. Up to 78% of template in Al-MCM-41 could be removed either by extraction with ordinary solvents or methanol-modified supercritical CO2, Complete template removal was achieved by calcination. Both, solvent and supercritical fluid extraction media influenced the structure, texture and acid properties of the resulting Al-MCM-41 materials and, consequently, their catalytic activity for the Friedel-Crafts acylation of 2-methoxynaphthalene. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:133 / 137
页数:5
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