Green chemistry - Reversible nonpolar-to-polar solvent

被引:801
作者
Jessop, PG [1 ]
Heldebrant, DJ
Li, XW
Eckert, CA
Liotta, CL
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Georgia Inst Technol, Sch Chem, Atlanta, GA 30332 USA
[3] Georgia Inst Technol, Sch Chem Engn, Atlanta, GA 30332 USA
关键词
D O I
10.1038/4361102a
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Imagine a smart solvent that can be switched reversibly from a liquid with one set of properties to another that has very different properties, upon command. Here we create such a system, in which a non-ionic liquid (an alcohol and an amine base) converts to an ionic liquid (a salt in liquid form) upon exposure to an atmosphere of carbon dioxide, and then reverts back to its non-ionic form when exposed to nitrogen or argon gas. Such switchable solvents should facilitate organic syntheses and separations by eliminating the need to remove and replace solvents after each reaction step.
引用
收藏
页码:1102 / 1102
页数:1
相关论文
共 5 条
[1]  
[Anonymous], 1999, CHEM SYNTHESIS USING
[2]   The reaction of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) with carbon dioxide [J].
Heldebrant, DJ ;
Jessop, PG ;
Thomas, CA ;
Eckert, CA ;
Liotta, CL .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (13) :5335-5338
[3]   Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: The accelerating effect of certain alcohols and amines [J].
Munshi, P ;
Main, AD ;
Linehan, JC ;
Tai, CC ;
Jessop, PG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :7963-7971
[4]   Activation of carbon dioxide by bicyclic amidines [J].
Pérez, ER ;
Santos, RHA ;
Gambardella, MTP ;
de Macedo, LGM ;
Rodrigues, UP ;
Launay, JC ;
Franco, DW .
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (23) :8005-8011
[5]  
SUBRAMANIAM B., 2002, CARBON DIOXIDE CONVE, P364