Polymer-supported synthesis of mono-substituted porphyrins

被引：7

作者：

Yang, QF ^{[1
]}

Streb, KK ^{[1
]}

Borhan, B ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 39期

关键词：

porphyrins; soluble polymers; cross-linked polymers; mono-substituted tetraarylporphyrins;

D O I：

10.1016/j.tetlet.2005.07.131

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anchoring of substituted benzaldehydes to soluble and insoluble polymers allows for the synthesis of mono-substituted tetraarylporphyrins without the production of di-, tri-, and tetra-substituted porphyrin side products. The exclusion of the aforementioned side products during the synthesis of mono-substituted tetraarylporphyrin acids greatly reduced the complexity during purification of the product. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6737 / 6740

页数：4

共 20 条

[1]

Chen SQ, 1997, J AM CHEM SOC, V119, P11355

[2]

DOLPHIN D, 1979, PORPHYRINS STRUCTURE, V1

[3]

Huang XF, 2000, CHEM-EUR J, V6, P216, DOI 10.1002/(SICI)1521-3765(20000117)6:2<216::AID-CHEM216>3.0.CO

[4]

2-1

[5] Absolute configurational assignments of secondary amines by CD-sensitive dimeric zinc porphyrin host [J].

Huang, XF ;

Fujioka, N ;

Pescitelli, G ;

Koehn, FE ;

Williamson, RT ;

Nakanishi, K ;

Berova, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) :10320-10335

[6] Zinc porphyrin tweezer in host-guest complexation: Determination of absolute configurations of diamines, amino acids, and amino alcohols by circular dichroism [J].

Huang, XF ;

Rickman, BH ;

Borhan, B ;

Berova, N ;

Nakanishi, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (24) :6185-6186

[7]

Huang XF, 2000, CHIRALITY, V12, P237, DOI 10.1002/(SICI)1520-636X(2000)12:4<237::AID-CHIR10>3.0.CO

[8]

2-6

[9]

KADISH KM, 2000, SYNTHESIS ORGANIC CH, V1

[10] Chiral recognition by CD-sensitive dimeric zinc porphyrin host.: 1.: Chiroptical protocol for absolute configurational assignments of monoalcohols and primary monoamines [J].

Kurtán, T ;

Nesnas, N ;

Li, YQ ;

Huang, XF ;

Nakanishi, K ;

Berova, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (25) :5962-5973

← 1 2 →